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Two methods exist: 2D and 3D laser marking. Precious metal items of art or jewelry are frequently hallmarked depending upon the requirements of the laws of either the place of manufacture or the place of import.

Where required to be hallmarked, semi-finished precious metal items of art or jewelry pass through the official testing channels where they are analyzed or assayed for precious metal content.

While different nations permit a variety of legally acceptable finenesses, the assayer is actually testing to determine that the fineness of the product conforms with the statement or claim of fineness that the maker has claimed usually by stamping a number such as for 18k gold on the item.

In the past the assay was conducted by using the touchstone method but currently most often it is done using X-ray Fluorescence XRF.

XRF is used because this method is more exacting than the touchstone test. The most exact method of assay is known as fire assay or cupellation. This method is better suited for the assay of bullion and gold stocks rather than works or art or jewelry because it is a completely destructive method.

The age-old touchstone method is particularly suited to the testing of very valuable pieces, for which sampling by destructive means, such as scraping, cutting or drilling is unacceptable.

A rubbing of the item is made on a special stone, treated with acids and the resulting color compared to references. Differences in precious metal content as small as 10 to 20 parts per thousand can often be established with confidence by the test.

It is not indicated for use with white gold, for example, since the color variation among white gold alloys is almost imperceptible.

The modern X-ray fluorescence is also a non-destructive technique that is suitable for normal assaying requirements. It typically has an accuracy of 2—5 parts per thousand and is well-suited to the relatively flat and large surfaces.

It is a quick technique taking about three minutes, and the results can be automatically printed out by the computer. It also measures the content of the other alloying metals present.

It is not indicated, however, for articles with chemical surface treatment or electroplated metals. The most elaborate, but totally destructive, assay method is the fire assay , or cupellation.

As applied to gold bearing metallics, as in hallmark assaying, it is also known as cupellation and can have an accuracy of 1 part in 10, In this process the article is melted, the alloys separated and constituents weighed.

Since this method is totally destructive, when this method is employed for the assay of jewelry, it is done under the guise of random or selective sampling.

For example, if a single manufacturer deposits a lot of rings or watch cases, while most are assayed using the non-destructive methods a few pieces from the lot are randomly selected for fire assay.

There are methods of assay noted above which are more properly suited for finished goods while other methods are suitable for use on raw materials before artistic workmanship has begun.

Raw precious metals bullion or metal stock are assayed by the following methods: silver is assayed by titration , gold is assayed by cupellation and platinum is assayed by ICP OES spectrometry.

From Wikipedia, the free encyclopedia. Redirected from Hallmarked. For other uses, see Hallmark disambiguation. For the meanings of gold standard hallmarks, see Carat purity.

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